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The molybdenum(VI) and tungsten(VI) complexes [MO2(L)] (M = Mo (1), W (2), H2L = bis(2-hydroxy-3,5-di-tert-butybenzyl)morpholinylethylamine) were synthesized and the complexes were used to catalyze oxotransfer reactions, viz. sulfoxidation, epoxidation and benzoin oxidation. For comparison, the same reactions were catalyzed using the known complexes [MO2(L′)] (M = Mo (3), W (4), H2L′ = bis(2-hydro

The concept of evaporation driven self-assembly of nanoparticles is exploited to fabricate three dimensional microstructures on textured superhydrophobic surfaces. The evaporative droplets always remain in Cassie–Baxter state during the process of drying. However, the wetting transition from Cassie to Wenzel state has been observed for pure water drop on similar surfaces. After complete evaporatio

Early agriculture can be detected in palaeovegetation records, but quantification of the relative importance of climate and land use in influencing regional vegetation composition since the onset of agriculture is a topic that is rarely addressed. We present a novel approach that combines pollen-based REVEALS estimates of plant cover with climate, anthropogenic land-cover and dynamic vegetation mo

We present results from the anodization of single crystal Al(100) and Al(111) surfaces and the aluminum alloy AA 6063 studied in situ by X-ray reflectivity and electrochemical impedance spectroscopy. We observe that the anodic oxide layer grows linearly with the anodization potential and that the thicknesses are similar for all samples. However, the thicknesses obtained from X-ray reflectivity are

In-plane cohesive failure of paperboard was characterized by short-span uniaxial tension tests. Six paperboards' qualities were experimentally investigated, from which cohesive stress-widening curves were extracted. A fracture energy was defined, expressed in the tensile strength and maximum slope of the cohesive stress-widening relation. Analytical cohesive relations were derived based on the ten

In parallel with five new scientific scenarios of alternative societal developments (shared socioeconomic pathways, SSPs), a wide range of literary representations of a future world in which climate change comes to matter have emerged in the last decade. Both kinds of narrative are important forms of “world-making.” This article initiates a conversation between science and literature through situa

Metal forming processes require wear-resistant tool surfaces in order to ensure a long life cycle of the expensive tools together with a constant high quality of the produced components. Thermal spraying is a relatively widely applied coating technique for the deposit of wear protection coatings. During these coating processes, heterogeneous coatings are deployed at high temperatures followed by q

Background and aims: Decomposition and transformation of organic matter (OM) in forest soils are conducted by the concomitant action of saprotrophic and mycorrhizal fungi. Here, we examine chemical changes in OM after fungal colonization in nitrogen fertilized and unfertilized soils from a Norway spruce forest. Methods: Sand-filled bags amended with composted maize leaves were placed in the forest

Ben-Israel and Vaidman (Found Phys 47:467–470, 2017) have raised objections to my arguments that there are cases where a quantum mechanical weak value can be said not to represent the system to which it pertains. They are correct in pointing out that some of my conclusions were too general. However, for weak values of projection operators my conclusions still stand.

The purpose of the Reliability-Based Design Optimization (RBDO) is to find the best compromise between safety and cost. Therefore, several methods, such as the Hybrid Method (HM) and the Optimum Safety Factor (OSF) method, are developed to achieve this purpose. However, these methods have been applied only on static cases and some special dynamic ones. But, in real mechanical applications, structu

Vitamin D and calcium are essential nutrients with a range of biological effects of public health relevance. This study aimed to validate a short food frequency questionnaire (SFFQ) against a three-day food record (3D record), assessing the intake of vitamin D and calcium in Swedish children during wintertime. In a double-blinded, randomized food-based intervention study on the effect of feeding d

Context. Determination of absolute parallaxes by means of a scanning astrometric satellite such as Hipparcos or Gaia relies on the short-term stability of the so-called basic angle between the two viewing directions. Uncalibrated variations of the basic angle may produce systematic errors in the computed parallaxes. Aims. We examine the coupling between a global parallax shift and specific variati

Spectroscopic studies have demonstrated that nearly all Galactic globular clusters (GCs) harbour multiple stellar populations with different chemical compositions. Moreover, colour-magnitude diagrams based exclusively on Strömgrem photometry have allowed us to identify and characterise multiple populations along the RGB of a large number of clusters. In this paper we show for the first time that S

Learning is often a central element of tourism. Tourists can learn actively, i.e. with a specific purpose, as well as passively through the comparison of values, norms and customs. It has been argued that travel supports active learning that has positive outcomes for sustainability, for instance, in the context of conservation. Yet, the complexity of active and passive learning processes and their

Context. The spatial distribution of elemental abundances in the disc of our Galaxy gives insights both on its assembly process and subsequent evolution, and on the stellar nucleogenesis of the different elements. Gradients can be traced using several types of objects as, for instance, (young and old) stars, open clusters, HII regions, planetary nebulae. Aims. We aim to trace the radial distributi

We apply molecular dynamic simulations to describe [C2mim+][Tf2N-] ionic liquids and its mixtures with solvents confined inside carbon nanopores. Both slit and cylindrical pores are modeled to determine the influence of pore geometry on the electric double layer (EDL) structure and capacitance. Two types of solvents are selected to dilute the ionic liquids in order to establish the effect of solve

We present the implementation of a platform for providing mobility and reliability to computational tasks that are executed in the access cloud. The platform is primarily aimed at providing an experimental tool for further studying of sophisticated techniques for task scheduling, placement and migration policies. In its current form, the platform supports streaming services but can be extended wit

The calculation of absorbed dose within patients during external photon beam radiotherapy is reviewed. This includes the modelling of the radiation source i.e. in most cases a linear accelerator (beam modelling) and examples of dose calculation algorithms applied within the patient i.e. the dose engine. For the first part - the beam modelling, the different sources in the treatment head as target,

The normoxic polymer gel dosimeter based on N-isopropyl acrylamide (NiPAM) is a promising full 3D-dosimeter with high spatial resolution and near tissue equivalency. NiPAM gel samples were irradiated to different doses using a linear accelerator. The absorbed dose was evaluated using MRI and statistical significance of the analysed data was calculated. The analysis was carried out using an in-hous