NMR studies of molecular mobility in a DNA-amphiphile complex
The molecular mobility in a hexagonal DNA-cationic surfactant complex is studied using H-1 and C-13 nuclear magnetic resonance spectroscopy. The charge-compensated complex can swell in water up to a content of approximately seven water molecules per charge. The NMR measurements show that in the dry state the alkyl chains of the surfactant have the properties of a disordered solid with internal mot