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Photofragmentation laser-induced fluorescence (PFLIF) is for the first time performed based on picosecond laser pulses for detection of hydroperoxyl radicals (HO2) in a stoichiometric laminar methane/air flame. Photofragmentation is performed with a pump laser pulse of 80 ps duration and a wavelength of 266 nm, whereupon the produced OH photofragments are detected by a second picosecond probe lase
