Structure of Thallium(Iii) Chloride, Bromide, and Cyanide Complexes in Aqueous-Solution
The structures of the hydrated thallium(III) halide and pseudohalide complexes, [TlX(n)(OH2)(m)]((3-n)+), X = Cl, Br, CN, in aqueous solution have been studied by a combination of X-ray absorption fine structure spectroscopy (XAFS), large-angle X-ray scattering (LAXS), and vibrational spectroscopic (Raman and IR) techniques including far-infrared studies of aqueous solutions and some solid phases