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Objectives: To quantify the influence of lifestyle factors on tumour necrosis factor inhibitor (TNFi) treatment response, in axial spondyloarthritis (axSpA). Methods: Data on biologics-naïve adults with axSpA were captured from European rheumatology registries. Information on lifestyle factors (smoking, overweight/obesity, and/or alcohol consumption) were identified ± 30 days of commencing their f
The investigation of carbon monoxide (CO) adsorption on the unreconstructed Ir(100)-(1 × 1) surface under ultra-high vacuum (UHV) conditions is studied with scanning tunneling microscopy (STM), low-energy electron diffraction (LEED), and high-resolution core-level spectroscopy (HRCLS). At a low coverage of 0.5 ML (monolayer), CO molecules adopt a previously documented c(2 × 2) structure, having CO
A novel approach combining 3D printing, phase inversion, and microwave plasma-enhanced chemical vapor deposition is presented. This technique enables the creation of carbon-based electrodes with precise micro- and nanoscale control, offering potential for sustainable and high-performance wastewater treatment applications. The synthesized 3D carbon scaffolds, enriched with B,N-doped carbon nanostru
Over the last century, district heating (DH) has only achieved global market shares of around 10 %. To reach its potential market shares of 25–50 % in Europe by 2050, growth must drastically accelerate. But deployment of DH is hindered by barriers, potentially slowing this fast-paced transition of the heat system. In this paper, we identify barriers to the deployment of DH through manual and GPT-a
The recognition of amine groups by ninhydrin, along with a simple mathematical algorithm, showed that di- and tripeptides derived from dietary protein are the major end products of protein digestion entering the blood postprandially. There are thousands of oligopeptides appearing in the gut during protein digestion. However, the presented study on a pig model clearly shows that peptides longer tha
A NNW-trending mafic dyke from the central-western Bastar craton yields a U[sbnd]Pb ID-TIMS baddeleyite age of 1944 ± 6 Ma. By correlating additional dykes with similar trend and geochemical characteristics, we identify a previously unrecognized dyke swarm, named herein the Pakhanjore swarm. Geochemical evidence suggests that the studied rocks are derived from partial melting of a spinel-rich, sha
Background: People seeking refuge and asylum must often endure diverse adversities before, during, and after migration, making them more susceptible to develop psychological problems. The effect of post-migration stressors on responsiveness to psychological treatment is unclear.Objectives: To: (1) evaluate the scope of the literature on the relation between post-migration stressors (e.g. struggles
A much debated topic in recent studies of ultrafast exciton dynamics in molecular aggregates has been the precise definition of the exciton coherence domain in the B850 aggregate of photosynthetic purple bacteria. In this work we compare several measures of exciton delocalization and their variation with temperature, inhomogeneous broadening, and time. We find that the exciton wave packet prepared
We report observations of ultrafast carotenoid band shifts correlated with energy transfer dynamics between bacteriochlorophyll (BChl) molecules within the peripheral light-harvesting complex (LH2) from the photosynthetic bacterium Rhodobacter sphaeroides. Direct excitation of the bacteriochlorophyll Q(y) bands yielded distinct changes in the carotenoid S2 absorption from 430 to 530 nm. Transient
The properties of elementary excited states in the B850 band of the peripheral light-harvesting antenna (LH2) of the photosynthetic purple bacterium Rhodobacter sphaeroides has been studied at room temperature by means of femtosecond transient absorption experiments combined with computer simulations. Polarized pump-probe kinetics have a fast component of 100 and 65 fs for the anisotropic and isot
The doorway-window representation of sequential pump-probe spectroscopy, derived by solving the nonlinear exciton equations, is used to study exciton dynamics in molecular aggregates. Exciton relaxation is incorporated through a multilevel Redfield relaxation superoperator calculated using the Brownian oscillator spectral density for the collective phonon coordinates. Optical pulses are included u
The multiexciton density matrix theory is utilized to achieve a microscopic description of exciton-exciton annihilation (EEA). We apply the theory to the 18 bacteriochlorophyll (BChl) molecules of the B850 ring of the light-harvesting complex LH2 of Rhodobacter sphaeroides. The simulation of the EEA process reproduces the intensity-dependent transient absorption kinetic experiments very well, and
The temporal evolution of the transient absorption response of light‐harvesting antennae and dye molecules was studied. Using 40—90 fs pulses coherent nuclear motions were observed in intact membrane‐bound photosynthetic light‐harvesting pigment‐protein complexes, bacteriochlorophyll α monomer and dye molecules in solutions. Computer simulations based on the harmonic Franck—Condon approximation an
Using terahertz and transient absorption spectroscopy, carrier dynamics in organo halide perovskite solar cell is probed. Charge generation is <100 fs, followed by 2 ps charge formation with balanced electron hole mobility of 20 cm2V-1s-1.
Femtosecond transient absorption measurements were performed on native and a series of reconstituted LH2 complexes from Rhodopseudomonas acidophila 10050 at room temperature. The reconstituted complexes contain chemically modified tetrapyrrole pigments in place of the native bacteriochlorophyll a-B800 molecules. The spectral characteristics of the modified pigments vary significantly, such tha
Energy transfer within the peripheral light-harvesting antenna of the purple bacteria Rhodobacter sphaeroides and Rhodopseudomonas palustris was studied by one- and two-color pump-probe absorption spectroscopy with approximately 100-fs tunable pulses at room temperature and at 77 K. The energy transfer from B800 to B850 occurs with a time constant of 0.7 +/- 0.05 ps at room temperature and 1.8 +/-
