Sm(II) and Yb(II) Assisted C-F Bond Activation of Monofluorinated Alkanes
In this study, the lanthanide complexes Sm(HMDS)2 (1), Yb(HMDS)2 (2), Sm(Cp*)2 (3), and Yb(Cp*)2 (4) were synthesized, and a new polymorph of 2 was identified via single- crystal X-ray diffraction (sc-XRD). Additionally, the previously unreported Yb(III) compound [YbI2(OPPh3)4]I was discovered as a probable disproportionation product of YbI2(OPPh3)4 and characterized via 31P{1H} NMR spectroscopy a