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Oxidation-reduction potential (ORP) as a tool for process monitoring of H2O2/LPMO assisted enzymatic hydrolysis of cellulose

Oxidation-reduction potential (ORP) is an environmental factor of importance in several biological conversion processes. Lytic polysaccharide monooxygenases (LPMOs) catalyze oxidative disruption of the cellulose chain in the presence of oxygen or hydrogen peroxide and increase enzymatic hydrolysis yields. However, the enzymes are also sensitive to oxidative damage and the level of oxidative agent

High-Fat Diet Enriched with Bilberry Modifies Colonic Mucus Dynamics and Restores Marked Alterations of Gut Microbiome in Rats

Scope: Emerging evidence suggests that high-fat diet (HFD) is associated with gut microbiome dysbiosis and related disorders. Bilberry is a prebiotic food component with known health benefits. Herein, the dynamics of the colonic mucus layer and microbiome during HFD and bilberry supplementation are addressed. Methods and results: The effects on colonic mucus thickness in vivo and gut microbiota co

Modes of Shopping Constituting a Local Street: A video-ethnography of shopping as a practice

In the last decades spatiotemporal manifestations of shopping are changed radically in conjunction with proliferation of car usage, internationalization of retail, and establishment of out-of-town malls. The social, cultural, and economic backgrounds of this axis alteration and its implication to the city life have been discussed thoroughly. However, the main empirical focus laid mostly on the mai

Implications of existing local (mal)adaptations for ecological forecasting under environmental change

Standing genetic variation represents a genetic load on population fitness but can also support a rapid response to short-term environmental change, and the greatest potential source of such standing genetic variation typically exists among locally adapted populations living along an environmental gradient. Here, we develop a spatially explicit simulation model to quantify the contribution of exis

In Situ Formation of Ge Nanoparticles by Annealing of Al-Ge-N Thin Films Followed by HAXPES and XRD

Ge nanoparticles embedded in thin films have attracted a lot of attention due to their promising optical and electronic properties that can be tuned by varying the particle size and choice of matrix material. In this study, Ge nanoparticle formation was investigated for Al-Ge-N based thin films by simultaneous measurements of HAXPES and grazing incidence XRD during in situ annealing in vacuum cond

A covariant formulation of finite plasticity with plasticity-induced evolution of anisotropy : Modeling, algorithmics, simulation, and comparison to experiments

Motivated by experimental findings on sheet-metal forming, this article concerns the modeling of evolving anisotropies in finite plasticity. A covariant formulation of plasticity is employed in conjunction with evolution equations for the structural tensors that characterize the symmetry group of the yield function. A specific model is implemented into a finite element code to simulate tension and

The electronic structure of ionic liquids based on the TFSI anion : A gas phase UPS and DFT study

The valence bands of [EMIM][TFSI], [DEME][TFSI] and [PYR1,4][TFSI] gas-phase ion pairs have been investigated using ultraviolet photoelectron spectroscopy (UPS). The photoelectron spectra are interpreted by using several density functional and ab initio calculation methods. Although the experimental vapor phase spectra are similar, the different calculation methods make different predictions about

Evidence for Mesoproterozoic collision, deep burial and rapid exhumation of garbenschiefer in the Namaqua Front, South Africa

Metamorphic provinces such as the ∼1 ​Ga Grenvillian, ∼400 ​Ma Caledonide and Triassic Qinling Provinces often contain rocks with high-pressure assemblages such as eclogites, which formed at mantle depths in subduction zones. These are evidence of the accretion of terranes by subduction of oceans and collision to form large tectonostratigraphic provinces. The Mesoproterozoic Namaqua-Natal Province

Design of kinetic models for assessment of critical aspects in bioprocess development : A case study of biohydrogen

The world faces major climate challenges and extensive efforts need to be taken to combat this issue. Replacing fossil-derived fuels and chemicals with renewables are one important step on the way. Hydrogen has a great potential as a renewable energy carrier for the transport sector and as a green chemical for the industry. Today, the production of hydrogen stems primarily from fossil resources. A

Neural-Network-Based Adaptive Control for Bilateral Teleoperation with Multiple Slaves under Round-Robin Scheduling Protocol

A neural-network-based adaptive control scheme is developed for bilateral teleoperation systems with single-master-multiple-slaves in the presence of dynamic uncertainties and communication constraint. Discrete-time data transmitting communication network with bandwidth limitation and time-varying communication delays is considered and the Round-Robin scheduling protocol is used to orchestrate the

Pacemaker treatment after Fontan surgery—A Swedish national study

Objective: Fontan surgery is performed in children with univentricular heart defects. Previous data regarding permanent pacemaker implantation frequency and indications in Fontan patients are limited and conflicting. We examined the prevalence of and risk factors for pacemaker treatment in a consecutive national cohort of patients after Fontan surgery in Sweden. Methods: We retrospectively reviewe

Local and average structure of Yb-doped ceria through synchrotron and neutron pair distribution function

As transport properties of doped ceria electrolytes depend significantly on the nature of the dopant and the defectivity, the design of new materials and devices requires proper understanding of the defect structure. Among lanthanide dopants, Yb shows some peculiar characteristics that call for a possible different defect structure compared to Gd and Sm conventional dopants, which could be linked

Statistical inference and time-frequency estimation for non-stationary signal classification

En signal är en fysisk kvantitet som varierar med någon oberoende variabel, t.ex. tid eller rum, som förmedlar information. En signal vars statistiska egenskaper är konstant i tid kallas stationär, medan signaler vars egenskaper varierar med tiden kallas icke-stationära, vilket är de vanligaste i naturen. Denna avhandling fokuserar på statistiska metoder för icke-stationära signaler. De applikatioThis thesis focuses on statistical methods for non-stationary signals. The methods considered or developed address problems of stochastic modeling, inference, spectral analysis, time-frequency analysis, and deep learning for classification. In all the contributions, an example of a biomedical application of the proposed method is provided, either to electroencephalography (EEG) data or to Heart Ra

Environmental water flow can boost foraging success of the juvenile rapa whelk Rapana venosa (Muricidae) in aquaculture tanks with still or flowing water : Indication of chemosensory foraging

Artificial breeding of Rapana venosa has been attempted in China, but the high mortality rate of rapa whelk juveniles (10–40 mm) seriously restricts the breeding success of this species in artificial cultivation and the overall aquaculture industry, and thus the scale of industrialization is far from being realized. One main factor was found to contribute to this high mortality rate: the low preda

From diffusion limited to incorporation limited growth of nanowires

We propose a model for the axial growth rate of nanowires grown by means of the vapor-liquid-solid mechanism. Our model is based on deposition-desorption-incorporation kinetics in steady state, and using this model we discuss nanowire growth in two experimentally relevant limits: mass transport limited growth and incorporation limited growth. We discuss our modeling results in view of experimental

Rapid nitrogen and phosphorus homeostasis transformation in Eupatorium adenophorum during invasion

Exotic plants can compete well with native species because many invasive species are considered better nutrient users in both low- and high-resource environments. However, whether invasive plants can outperform native plants at all stages of invasion is not very clear. We investigated the nitrogen (N), phosphorus (P) and N:P homeostasis of an invasive Eupatorium adenophorum and a co-occurring nati

The geopolitics of metals and metalloids used for the renewable energy transition

This study examines the geopolitical role of 14 metals and metalloids needed for renewable energy technologies. The analysis focuses on three factors with potential geopolitical importance: the geographic concentration of resources, potential revenues of resources rich countries and the size of total global markets. The geographic concentration of most of the fourteen studied metals and metalloids

Redox-induced structural changes in the di-iron and di-manganese forms of Bacillus anthracis ribonucleotide reductase subunit NrdF suggest a mechanism for gating of radical access

Class Ib ribonucleotide reductases (RNR) utilize a di-nuclear manganese or iron cofactor for reduction of superoxide or molecular oxygen, respectively. This generates a stable tyrosyl radical (Y·) in the R2 subunit (NrdF), which is further used for ribonucleotide reduction in the R1 subunit of RNR. Here, we report high-resolution crystal structures of Bacillus anthracis NrdF in the metal-free form

More Power to the People: : Electricity Adoption, Technological Change and Social Conflict

There is a wide-spread concern that technical change may spur social conflicts, especially if workers are replaced with machines. To empirically analyze whether job destruction drives protests, we study a historical example of a revolutionary new technology: the adoption of electricity. Focusing on the gradual roll-out of the Swedish electricity grid between 1900 and 1920 enables us to analyze 2,4

Longitudinal evaluation of periodontitis and tooth loss among older adults

Aim: To evaluate pattern of change in periodontal variables and tooth loss in a twelve-year follow-up study of older adults living in Sweden. Methods: In a prospective population study of older adults, a clinical examination and radiographic dental examination were performed at baseline (2001–2003) and after 12 years (2013–2015). In 375 individuals, the number and proportion of sites with a distan