Self-diffusion study of micelles in poly(oxyethylene)-polydimethylsiloxane diblock copolymer and poly(oxyethylene) alkyl ether systems
Self-diffusion constants of amphiphilic molecules in D2O solutions of mixed poly(oxyethylene)-polydimethylsiloxane diblock copolymer (POE-PDMS, SimC3EOn) and poly(oxyethylene) dodecyl ether (C12EOn) were measured by pulsed-field-gradient NMR method. In the D2O/Si25C3EO51.6/C12EO8 or D2O/Si52C3EO51.6/Cl2EO8 systems, small and large micelles coexist in a wide range of SimC3EO51.6 fraction in total a