Metal ion coordination at the water-manganite (gamma-MnOOH) interface I. An EXAFS study of cadmium(II)
The local structure of Cd(II) surface complexes adsorbed onto manganite (gamma-MnOOH) has been investigated by extended X-ray absorption fine structure (EXAFS) spectroscopy. Adsorption experiments were carried out within the pH range 7.4-9.8 and with surface coverage from 2.2 to 8.9 mu mol/m(2). Quantitative analysis of the EXAFS spectra shows little difference in the local coordination environmen
